Synthetic studies on aphidicolane and stemodane diterpenes. III. An alternative stereoselective access to aphidicolane-type B/C/D-ring system

DOI: 10.1248/cpb.42.1756

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 1756 - 1759 (1994)

Update date:2022-08-03

Topics:

Authors:

Tanaka Tanaka

Murakami

Okuda Okuda

Kuroda Kuroda

Inoue Inoue

Kamei Kamei

Murata Murata

Yoshino Yoshino

Imanishi

Iwata Iwata

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Article abstract of DOI:10.1248/cpb.42.1756

Compound 2, corresponding to the B/C/D-ring for aphidicolane-type diterpenes, was synthesized stereoselectively from a perhydroindane derivative (3) which was obtained by rhodium-alumina catalyzed hydrogenation of an indane ester (4) as a key step.

Full text of DOI:10.1248/cpb.42.1756

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