Synthesis of 4-O-acetyl-L-rhodinopyranose via a tandem Sharpless asymmetric dihydroxylation/lipase-catalyzed transesterification

DOI: 10.1016/0040-4039(95)00778-B

Source and publish data:

Tetrahedron Letters p. 4193 - 4196 (1995)

Update date:2022-08-03

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Authors:

Sobti Sobti

Sulikowski

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Article abstract of DOI:10.1016/0040-4039(95)00778-B

An enantioselective synthesis of the trideoxy sugar 4-O-acetyl-L-rhodinopyranose (7) is described. A key feature of the synthetic strategy is a Sharpless asymmetric dihydroxylation followed by a lipase-mediated mono-esterification of the resultant diol (3 → 4 → 6).

Full text of DOI:10.1016/0040-4039(95)00778-B

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