EPC Synthesis of 6-Substituted 2-Oxo-cyclohexanecarboxylates via Conjugate Addition of Cuprates to Asymmetric Shielded 2-Oxo-cyclohexenecarboxylates

DOI: 10.1016/00404-0399(50)0886H-

Source and publish data:

Tetrahedron Letters p. 4773 - 4776 (1995)

Update date:2022-08-03

Topics:

Authors:

Urban, Ernst

Riehs, Gerhard

Knuehl, Guido

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/00404-0399(50)0886H-

Asymmetric shielded 2-oxo-cyclohexenecarboxylates 6n and 6x were prepared by transesterification of 2-oxo-cyclohexanecarboxylate 2 with camphor derived concave alcohols 1n and 1x and by subsequent introduction of a double bond via phenylselenides.Diastere

Full text of DOI:10.1016/00404-0399(50)0886H-

Products guided by the article

Product name:(S)-2-Hydroxy-6-methyl-cyclohex-1-enecarboxylic acid (1R,2S,3R,4S)-3-[benzenesulfonyl-(3,5-dimethyl-phenyl)-amino]-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl ester

Cas No:170211-91-3

R&D Labs maybe for 170211-91-3

Liao Cheng All Win Chemicals Co.,LTD

Contact:86+0635-2991582

Address:Room 402,Unit 1,No.27 building.Zhong tong shi dai haoyuan,liaocheng city,Shan dong Province.China
Hangzhou Haiqiang Chemical Co.,Ltd.

Contact:+86-571-86960370

Address:Add: 5/F, Around Town North Road,No. 10, Hangzhou, Zhejiang,China
Xi'an caijing Opto-Electrical Science & Technology Co., LTD

Contact:+86-29-88294447

Address:NO.168 Zhangba Rd. East, Xi'an, P.R.China
Disynthesis Chemical Technology Co. Ltd.

Contact:+86-571-88194596

Address:Dengyun road 380, Gongshu district, Hangzhou city, China
MedicalChem(Yancheng)Manuf.Co.,Ltd.

Contact:+86-515-84383366

Address:Touzeng BinHai, YanCheng City, JiangSu Province, China

Relevant to this article

Total synthesis of brevetoxin B. 2. Second generation strategies and construction of the dioxepane region [DEFG]

Doi:10.1021/ja00146a009
(1995)
Auxiliary-directed, asymmetric complexation and metal-promoted higher-order cycloaddition in the cycloheptatriene series

Doi:10.1021/ja00139a019
(1995)
The synthesis of (4E)-N-(4-chlorophenyl)-5-substituted-2-diazo-3-oxopent-4- enoic acid amides

Doi:10.1002/jccs.200500141
(2005)
Lithium derivatives from enatiomerically pure 2-(2'-haloethyl) dioxolanes: Formation and use as chiral propanol homoenolate synthons

Doi:10.1016/0957-4166(95)00225-E
(1995)
Stereoselective synthesis of α,α'-bridged bis(α-alanine) derivatives

Doi:10.1016/S0040-4020(98)00208-7
(1998)
A Facile Stereoselective Route to a C/D-Ring Synthon for 20-Epi-22-oxavitamin D₃ Analogues

Doi:10.1039/c39950001959
(1995)

Article Doi