EPC Synthesis of 6-Substituted 2-Oxo-cyclohexanecarboxylates via Conjugate Addition of Cuprates to Asymmetric Shielded 2-Oxo-cyclohexenecarboxylates

DOI: 10.1016/00404-0399(50)0886H-

Source and publish data:

Tetrahedron Letters p. 4773 - 4776 (1995)

Update date:2022-08-03

Topics:

Authors:

Urban, Ernst

Riehs, Gerhard

Knuehl, Guido

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/00404-0399(50)0886H-

Asymmetric shielded 2-oxo-cyclohexenecarboxylates 6n and 6x were prepared by transesterification of 2-oxo-cyclohexanecarboxylate 2 with camphor derived concave alcohols 1n and 1x and by subsequent introduction of a double bond via phenylselenides.Diastere

Full text of DOI:10.1016/00404-0399(50)0886H-

Products guided by the article

Product name:(S)-2-Hydroxy-6-methyl-cyclohex-1-enecarboxylic acid (1R,2S,3R,4S)-3-[benzenesulfonyl-(3,5-dimethyl-phenyl)-amino]-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl ester

Cas No:170211-91-3

R&D Labs maybe for 170211-91-3

Suzhou Health Chemicals Co., Ltd.

website:http://www.healthchems.com

Contact:13776257979

Address:No. 338, Jingang Avenue,
Hangzhou Chemfar Ltd.

Contact:+86-571-87859231, 87859237, 87859239

Address:1606,Huarong Times Mansion, No.3880 Jiangnan Avenue, Binjiang District, Hangzhou, China, 310053
XZL BIO-TECHNOLOGY CO., LTD.

Contact:0086 533 2282832

Address:Zibo，Shandong
Quhua Zhongxing Refrigeration Technology Co.,Ltd.

Contact:+86-5708886618

Address:318 Bulding 2, No.866 Quhua Rd.,Kecheng District
Beijing Pure Chem Co.,Ltd.

Contact:+86-10-83993285

Address:Rm.1708, Haobai Tower, Building 6, No.50, North Road, West Third Ring, Haidian District, Beijing, China

Relevant to this article

Total synthesis of brevetoxin B. 2. Second generation strategies and construction of the dioxepane region [DEFG]

Doi:10.1021/ja00146a009
(1995)
Auxiliary-directed, asymmetric complexation and metal-promoted higher-order cycloaddition in the cycloheptatriene series

Doi:10.1021/ja00139a019
(1995)
The synthesis of (4E)-N-(4-chlorophenyl)-5-substituted-2-diazo-3-oxopent-4- enoic acid amides

Doi:10.1002/jccs.200500141
(2005)
Lithium derivatives from enatiomerically pure 2-(2'-haloethyl) dioxolanes: Formation and use as chiral propanol homoenolate synthons

Doi:10.1016/0957-4166(95)00225-E
(1995)
Stereoselective synthesis of α,α'-bridged bis(α-alanine) derivatives

Doi:10.1016/S0040-4020(98)00208-7
(1998)
A Facile Stereoselective Route to a C/D-Ring Synthon for 20-Epi-22-oxavitamin D₃ Analogues

Doi:10.1039/c39950001959
(1995)

Article Doi