EPC Synthesis of 6-Substituted 2-Oxo-cyclohexanecarboxylates via Conjugate Addition of Cuprates to Asymmetric Shielded 2-Oxo-cyclohexenecarboxylates

DOI: 10.1016/00404-0399(50)0886H-

Source and publish data:

Tetrahedron Letters p. 4773 - 4776 (1995)

Update date:2022-08-03

Topics:

Authors:

Urban, Ernst

Riehs, Gerhard

Knuehl, Guido

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/00404-0399(50)0886H-

Asymmetric shielded 2-oxo-cyclohexenecarboxylates 6n and 6x were prepared by transesterification of 2-oxo-cyclohexanecarboxylate 2 with camphor derived concave alcohols 1n and 1x and by subsequent introduction of a double bond via phenylselenides.Diastere

Full text of DOI:10.1016/00404-0399(50)0886H-

Products guided by the article

Product name:(S)-2-Hydroxy-6-methyl-cyclohex-1-enecarboxylic acid (1R,2S,3R,4S)-3-[benzenesulfonyl-(3,5-dimethyl-phenyl)-amino]-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl ester

Cas No:170211-91-3

R&D Labs maybe for 170211-91-3

shandong zhongke taidou chemical co.,ltd

Contact:86-531-88682301

Address:Jinan shandong Province CHina
Tianjin Ingenochem Technology Co.,Ltd

Contact:+86-22-23677060

Address:Hitech Green Industry Park K2-9-602, Nankai district
EnBridge PharmTech Co., Ltd.

website:http://www.enbridgepharm.com

Contact:+86-510-83591909

Address:Huishan Zone, Wuxi City, Jiangsu Province, P.R.China
Okeanos Tech.Co.,LTD

Contact:+86-10-62651721

Address:29 Yongxing Road, Daxing District,Beijing China
sichuan tiancai fine co LTD.

website:http://www.tcfinechem.com/

Contact:18681346930

Address:baifu town,whou district

Relevant to this article

Total synthesis of brevetoxin B. 2. Second generation strategies and construction of the dioxepane region [DEFG]

Doi:10.1021/ja00146a009
(1995)
Auxiliary-directed, asymmetric complexation and metal-promoted higher-order cycloaddition in the cycloheptatriene series

Doi:10.1021/ja00139a019
(1995)
The synthesis of (4E)-N-(4-chlorophenyl)-5-substituted-2-diazo-3-oxopent-4- enoic acid amides

Doi:10.1002/jccs.200500141
(2005)
Lithium derivatives from enatiomerically pure 2-(2'-haloethyl) dioxolanes: Formation and use as chiral propanol homoenolate synthons

Doi:10.1016/0957-4166(95)00225-E
(1995)
Stereoselective synthesis of α,α'-bridged bis(α-alanine) derivatives

Doi:10.1016/S0040-4020(98)00208-7
(1998)
A Facile Stereoselective Route to a C/D-Ring Synthon for 20-Epi-22-oxavitamin D₃ Analogues

Doi:10.1039/c39950001959
(1995)

Article Doi