Samarium(II) Iodide Promoted Ring Contraction of Carbohydrate Derivatives: an Expeditious Synthesis of Functionalised Cyclopentanes

DOI: 10.1039/c39950001373

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1373 - 1374 (1995)

Update date:2022-08-02

Topics:

Authors:

Chenede, Alain

Pothier, Paul

Sollogoub, Matthieu

Fairbanks, Antony J.

Sinay, Pierre

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39950001373

Aldehydo methyl pyranosides undergo ring contraction induced by treatment with samarium(ii) iodide, in the presence of HMPA and tert-butyl alcohol, to give highly functionalised cyclopentanes.

Full text of DOI:10.1039/c39950001373

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:(3R,4R)-3,4-Bis-benzyloxy-hexane-1,6-diol

Cas No:170639-47-1

R&D Labs maybe for 170639-47-1

Hangzhou GreenCo Science & Technology Co., Ltd.

Contact:86-571-88257303

Address:1713 Room,Jingui Building,Gudun Road,Xihu District,Hangzhou,China
jiangsu senxuan pharmaceutical and chemical co.,ltd

Contact:86-523-87982810

Address:hongqiao industrial zone,taixing,jiangsu china
MTT Pharma & Bio-technology Co.,Ltd(expird)

Contact:+86-21-58407925

Address:Room2019, Building C, Tomson Center, No.158, Zhang Yang Road, Shanghai, China
Chongqing Rong＆Quan Pharmaceutical Technology Co. , Ltd.

Contact:86-023-65268721

Address:No. 7, Manshanhong Village, Pingdingshan, Shapingba District, Chongqing Province, China
Shandong Ailitong New Material Co.,Ltd

Contact:+86-536-3226266

Address:zhongjia village, putong town , qingzhou city,Shandong Province,China

Relevant to this article

Cleavage of C-Si bond by intramolecular nucleophilic attack: Lithiation-promoted formation of siloles from 1-bromo-4-trisubstituted silyl-1,3-butadiene derivatives

Doi:10.1016/j.tetlet.2004.11.098
(2005)
Asymmetric protected enoates as key intermediates towards an EPC synthesis of (+)-heptelidic acid

Doi:10.1016/0040-4039(95)01538-S
(1995)
An enantioselective synthesis of (11R,12S,13S,9Z,15Z)-9,12,13-trihydroxyoctadeca-9,15-dienoic acid, a self-defensive substance against rice blast disease

Doi:10.1246/cl.1995.763
(1995)
Synthesis, bioactivation and anti-HIV activity of 4-acyloxybenzyl bis(nucleosid-5'-yl) phosphates

Doi:10.1080/15257779508009491
(1995)
Synthesis of chiral N-alkyl-cyclopentadienyl sulfonamides

Doi:10.1016/0957-4166(95)00264-P
(1995)
Doi:10.1039/j39670001762
(1967)

Article Doi