Samarium(II) Iodide Promoted Ring Contraction of Carbohydrate Derivatives: an Expeditious Synthesis of Functionalised Cyclopentanes

DOI: 10.1039/c39950001373

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1373 - 1374 (1995)

Update date:2022-08-02

Topics:

Authors:

Chenede, Alain

Pothier, Paul

Sollogoub, Matthieu

Fairbanks, Antony J.

Sinay, Pierre

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39950001373

Aldehydo methyl pyranosides undergo ring contraction induced by treatment with samarium(ii) iodide, in the presence of HMPA and tert-butyl alcohol, to give highly functionalised cyclopentanes.

Full text of DOI:10.1039/c39950001373

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:(3R,4R)-3,4-Bis-benzyloxy-hexane-1,6-diol

Cas No:170639-47-1

R&D Labs maybe for 170639-47-1

Tianjin Emulsion Science&Technology Development Co.,Ltd

Contact:13901380442

Address:Vake Garden New Town New Yi Bai Road Beichen District Tianjin,China
Chongqing KonAo Health Co.,Ltd

Contact:13687578375

Address:wuhan hubei china
ShiJiaZhuang Dowell Chemical Co.,Ltd.

website:http://www.dowechem.com

Contact:+86-13463963265

Address:Xiyangling village, high tech Zone, Shijiazhuang，Hebei, China
Qingdao Kylin Trading Co., Ltd.

Contact:0086-532-68979884/58972912/68972263/65/88171519

Address:Room 2308,A building International Trade Center No.230 Changjiang Middle Road of Qingdao Economic Development Zone,Shandong,China.
SHIJIAZHUANG CHENSHI IMPORT AND EXPORT CO.,LTD

Contact:+86-311-89871056

Address:RM2017 BUILDING CTIANSHAN GALAXY PLAZA,NO168 CHANGJIANG ROAD,GAOXIN DISTRICT,SHIJIAZHUANG CITY, HEBEI,CHINA

Relevant to this article

Cleavage of C-Si bond by intramolecular nucleophilic attack: Lithiation-promoted formation of siloles from 1-bromo-4-trisubstituted silyl-1,3-butadiene derivatives

Doi:10.1016/j.tetlet.2004.11.098
(2005)
Asymmetric protected enoates as key intermediates towards an EPC synthesis of (+)-heptelidic acid

Doi:10.1016/0040-4039(95)01538-S
(1995)
An enantioselective synthesis of (11R,12S,13S,9Z,15Z)-9,12,13-trihydroxyoctadeca-9,15-dienoic acid, a self-defensive substance against rice blast disease

Doi:10.1246/cl.1995.763
(1995)
Synthesis, bioactivation and anti-HIV activity of 4-acyloxybenzyl bis(nucleosid-5'-yl) phosphates

Doi:10.1080/15257779508009491
(1995)
Synthesis of chiral N-alkyl-cyclopentadienyl sulfonamides

Doi:10.1016/0957-4166(95)00264-P
(1995)
Doi:10.1039/j39670001762
(1967)

Article Doi