Samarium(II) Iodide Promoted Ring Contraction of Carbohydrate Derivatives: an Expeditious Synthesis of Functionalised Cyclopentanes

DOI: 10.1039/c39950001373

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1373 - 1374 (1995)

Update date:2022-08-02

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Authors:

Chenede, Alain

Pothier, Paul

Sollogoub, Matthieu

Fairbanks, Antony J.

Sinay, Pierre

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Article abstract of DOI:10.1039/c39950001373

Aldehydo methyl pyranosides undergo ring contraction induced by treatment with samarium(ii) iodide, in the presence of HMPA and tert-butyl alcohol, to give highly functionalised cyclopentanes.

Full text of DOI:10.1039/c39950001373

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