Synthesis and Crystal Structure of a New C2-Symmetric Chiral Bis-sulfoxide Ligand and Its Palladium(II) Complex

Article abstract of DOI:10.1016/0040-4039(95)01701-I

A new chiral bis-sulfoxide ligand (S,S)-1,2-bis(p-tolylsulfinyl)benzene (BTSB), which possesses S,S-bidentate chelating donor atoms on an aromatic ring, was synthesized.Pd, Rh, and Ru readily gave adducts with this ligand.The crystal structure of PdCl2