Journal of Organometallic Chemistry p. 35 - 46 (1995)
Update date:2022-07-30
Topics:
Ancker, Tania R. van den
Harvey, Steven
Raston, Colin L.
Reactions of polystyrene supported magnesium anthracene containing radical anion and dianion sites, 7,7', with benzylic chlorides or bromides, affords Grignard reagents, RMgX, in modest to high yields, in THF at -10 deg C to 20 deg C.Novel benzylic-type Grignard reagents prepared in high yield include those of 2,6-(dichloromethyl)pyridine, 2,6-(dibromomethyl)pyridine, 2,2',2"-trispyridylmethylchloride, 2-methoxy-3-methyl-1-benzylchloride, 2,4-dimethoxy-5-methyl-1-benzylchloride, 3,5-dimethoxy-4-methyl-1-benzylchloride, 2,4,6-trimethoxy-3-methyl-1-benzylchloride, and 2,5-dimethoxybenzylchloride.Selected allylic halides similarly yield Grignard reagents.Keywords: Polymer; Magnesium; Anthracene; Grignard Reagent; Benzylic halide; Styrene
View MoreShanghai Yuking Water Soluble Material Tech Co., Ltd
Contact:86-21-68286299
Address:4F, 13B, No. 600, South Xinyuan Road 201306, Shanghai, China
Contact:86-532-68629711 13780605697
Address:NO 220 YANAN 3 ROAD,(POST ADMINISTRATION BUILDING),QINGDAO,CHINA
Suzhou Chiral Pharmaceuticals Co., Ltd.
Contact:86-0512-63197058
Address:Building A, No. 2358, Chang'an Road, Wujiang Science Park
Shaanxi HuaTai Bio-fine chemical company Ltd
Contact:86-029-87862197
Address:No. 5, 3rd Floor, 29 Yanta North Road, Beilin Dist.
Shanghai Pengkai Chemical Co.,Ltd
Contact:+86-21-60526671
Address:No.4226 Duzhuang Rd Minhang District Shanghai China
Doi:10.1021/jo0493469
(2004)Doi:10.1021/jm0004289
(2001)Doi:10.1016/j.phytol.2020.01.018
(2020)Doi:10.1021/ja01265a049
(1939)Doi:10.1039/b008683p
(2001)Doi:10.1021/acs.joc.0c01150
(2020)