Preparation of some cyclopentadienyl titanium complexes and crystal structure of (η5-pentamethylcyclopentadienyl) {(1R,2S,3R)-exo-3[(R)-2-phenyl-2-olato-ethyl] sulphenyl-1,7,7-trimethylbicyclo[2.2.1]heptan-2-olato} chlorotitanium(IV): [Cp*Ti(OC18H24SO)Cl]

Article abstract of DOI:10.1016/0277-5387(95)00113-7

The reaction of (1R,2S,3R)-exo-3[(R)-2-phenyl-2-hydroxyethyl]sulphenyl-1,7,7-trimethylbicyclo[2.2.1]heptan-2-ol (1) with Cp*TiCl3 in the presence of Et3N furnishes the product Cp*Ti(OC18H24SO)Cl in high yield {Cp*=pentamethylcyclopentadienyl; OC18H24SO=(1