
Journal of the Chemical Society. Chemical communications p. 3 - 5 (1989)
Update date:2022-07-30
Topics: Cyclisation Intramolecular Electrophilic Aromatic Substitution
Abramivitch, Rudolph A.
Chinnasamy, Pennamuthiriar
Evertz, Kaspar
Huttner, Gottfried
The delocalised ?-cations from 1-(m-nitreniobenzyl)-1,2,3,4-tetrahydroisoquinolines cyclise to 9- and 11-aminoaprophines, but the p-nitrenium isomers do not form a 5-membered ring uless the ring undergoing attack is strongly activated; on the other hand,
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