Remarkably high diastereoselective exo Diels-Alder reactivity of 4-vinyl isothiazoline-3-one-1-oxides: The sulphoxide syn effect

DOI: 10.1016/0040-4039(95)01570-8

Source and publish data:

Tetrahedron Letters p. 7713 - 7716 (1995)

Update date:2022-08-04

Topics:

Authors:

Bell Bell

Fishwick

Reed Reed

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Article abstract of DOI:10.1016/0040-4039(95)01570-8

Semi cyclic sulphoxide containing dienes, 4-vinyl-1,2-isothiazoline-3-one-1-oxides, generated in situ via Stille coupling methodology dimerise with remarkably high diastereoselectivity via an unusual exo syn transition state. X-ray analysis confirms the d

Full text of DOI:10.1016/0040-4039(95)01570-8

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Product name:2-(S)-α-methylbenzyl-4-bromo-1,2-isothiazoline-3-one-1-(S)-oxide

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