Tetrahedron p. 12239 - 12256 (1995)
Update date:2022-08-04
Topics:
Shima, Hidetaka
Furukawa, Naomichi
1,8-Bis(allylthio)-and 1,8-bis(allylseleno)naphthalene monooxides underwent facile multiallylic rearrangements to give 2-allyl-substituted naphtho<1,8-cd>-1,2-dithioles and naphtho<1,8-cd>-1,2-diselenoles under mild conditions via the sulfur-sulfur and selenium-selenium through-space interaction.The mechanism for the reaction has been determined by D-tracer and cross-over experiments.
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(1965)
