Total Synthesis of 12-epi-PGF2α

DOI: 10.1016/0040-4039(95)02390-9

Source and publish data:

Tetrahedron Letters p. 779 - 782 (1996)

Update date:2022-09-26

Topics:

Authors:

Hwang, Seong-Woo

Adiyaman, Mustafa

Khanapure, Subhash P.

Rokach, Joshua

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Article abstract of DOI:10.1016/0040-4039(95)02390-9

A novel synthesis of 12-epi-PGF_2α 5 is described. The key synthon 11, which has been used as a starting point for the synthesis, is produced by a radical cyclization process using thionocarbonate 9a. The radical cyclization of 9a to 11 has been studied in some detail.

Full text of DOI:10.1016/0040-4039(95)02390-9

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Product name:Benzoic acid (3aR,4R,5R,6aS)-5-hydroxy-2-oxo-hexahydro-cyclopenta[b]furan-4-ylmethyl ester

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