A convenient approach to diastereomerically pure 1,3,4-trisubstituted pyrrolidin-2-ones by intramolecular cyclisation of N-(2-alken-1-yl)amides mediated by Mn(III). An entry to both (R)- and (S)-3-pyrrolidineacetic acid

DOI: 10.1016/0040-4020(95)00939-6

Source and publish data:

Tetrahedron p. 1069 - 1084 (1996)

Update date:2022-08-04

Topics:

Authors:

Galeazzi, Roberta

Mobbili, Giovanna

Orena, Mario

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Article abstract of DOI:10.1016/0040-4020(95)00939-6

The oxidative cyclisation of a series of either (S)-N-(2-alken-1-yl)-N-(1-phenyleth-1-yl)-acetoacetamides 5a-d and methoxycarbonylacetamides 6a-b, performed by using Mn(OAc)₃ · 2H₂O and Cu(OAc)₂ · H₂O in acetic

Full text of DOI:10.1016/0040-4020(95)00939-6

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