Metal control of non-polar binding shape selectivity

DOI: 10.1016/S0040-4039(99)01579-8

Source and publish data:

Tetrahedron Letters p. 7641 - 7644 (1999)

Update date:2022-07-31

Topics:

Authors:

Wang, Fen

Schwabacher, Alan W.

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Article abstract of DOI:10.1016/S0040-4039(99)01579-8

Ligand 1 forms a hydrophobic cavity upon binding to metals, the shape of which depends on the metal. A reversal in binding preference for naphthalene or biphenyl groups is found when the metal is changed from zinc to copper, with a selectivity change of 260 fold.

Full text of DOI:10.1016/S0040-4039(99)01579-8

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