Tetrahedron Letters p. 2629 - 2630 (1996)
Update date:2022-08-05
Topics:
Chavan, Subhash P.
Ravindranathan
Patil, Sachindra S.
Dhondge, Vijay D.
Dantale, Shuhhada W.
Synthesis of α-Cuparenone is described. The key step involved are photorearrangement of α-halo arylketone (4) to 1-methyl-1-(p-tolyl)acetic acid (5) and extremely mild, essentially neutral, room temperature/3-aza-claisen reaction of N-allylamide (6).
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Doi:10.1021/jm00310a043
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(1996)
