
Tetrahedron Letters p. 7043 - 7046 (1999)
Update date:2022-08-04
Topics:
Koeller, Sylvain
Lellouche, Jean-Paul
O-tert-Butyldimethylsilylated (O-TBDMS) or O-triethylsilylated (O-TES) alcohols were converted in one step to their corresponding formates under Vilsmeier-Haack conditions (POCl3/DMF). The scope and limitations of this novel reaction for interconverting alcohol protecting groups are described.
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