Synthesis and characterization of copper(I) and silver(I) complexes containing thioamide ligands

Article abstract of DOI:10.1080/00945719608004331

Mononuclear complexes of the type (Ph₃P)₂MLX, where M = Cu, Ag; X = Cl, Br; L = dithiooxamide, thiourea, aminothiourea, have been synthesized and characterized by elemental analyses and IR spectra. The X-ray crystallographic structure determination of (Ph₃P)₂Cu(C₂H₄N₂S ₂)Br is reported. Dithiooxamide acts as a monodentate ligand through one S atom coordinated to Cu. The coordination of the Cu atom is a distorted tetrahedron with a Cu-Br distance of 2.482(3) and Cu-S distance of 2.356(5) A.

Full text of DOI:10.1080/00945719608004331

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Synthesis and Reactivity in
Inorganic and Metal-Organic
Chemistry
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Synthesis and
Characterization of Copper(I)
and Silver(I) Complexes
Containing Thioamide
Ligands
De-liang Long a , Dong-xiang Zeng a , Xin-quan
Xin a , Xiao-ying Huang b & Bei-sheng Kang b
a State Key Laboratory of Coordination
Chemistry , Coordination Chemistry Institute,
Nanjing University , Nanjing, 210093, P. R. China
b State Key Laboratory of Structural Chemistry ,
Fujian Institute of Research on the Structure of
Matter, Chinese Academy of Science , Fuzhou,
Fujian, 350002, P. R. China
Published online: 21 Aug 2006.
To cite this article: De-liang Long , Dong-xiang Zeng , Xin-quan Xin , Xiao-
ying Huang & Bei-sheng Kang (1996) Synthesis and Characterization of
Copper(I) and Silver(I) Complexes Containing Thioamide Ligands, Synthesis
and Reactivity in Inorganic and Metal-Organic Chemistry, 26:5, 723-733, DOI:
10.1080/00945719608004331
To link to this article: http://dx.doi.org/10.1080/00945719608004331
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