Polymeric and Bimetallic Complexes of Diisopropyl Monothiophosphate

DOI: 10.1039/DT9950002369

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2369 - 2376 (1995)

Update date:2022-07-31

Topics:

Authors:

Phillips, Julian R.

Poat, Julia C.

Slawin, Alexandra M. Z.

Williams, David J.

Wood, Paul T.

Woollins, J. Derek

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Article abstract of DOI:10.1039/DT9950002369

The single state preparation of Mn (n = 2, M = Zn 1, Co 2 or Cd 3; n = 1, M = NH4(1+) 4) from HPO(O-i-Pr)2, sulfur and ZnO, CoCO3, CdCO3 or NH3 has been achieved.The reaction of 1 with cis- and (M = Pt or Pd) gave <(PMe2Ph)2Pt2ZnCl2> 5 and <(PMe2Ph)M3ZnCl> (M = Pd 6 or Pt 7) respectively.The crystal structures of 3, 6 and 7 have been determined.The cadmium complex 3 exists as Cd23 units linked by additional monothiophosphate ligands into polymeric chains.Complexes 6 and 7 are isomorphous and contain tetrahedral zinc centres linked to square-planar platinum atoms with polymer formation deing inhibited by the presence of PMe2Ph ligands.

Full text of DOI:10.1039/DT9950002369

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