Polymeric and Bimetallic Complexes of Diisopropyl Monothiophosphate

DOI: 10.1039/DT9950002369

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2369 - 2376 (1995)

Update date:2022-07-31

Topics:

Authors:

Phillips, Julian R.

Poat, Julia C.

Slawin, Alexandra M. Z.

Williams, David J.

Wood, Paul T.

Woollins, J. Derek

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9950002369

The single state preparation of Mn (n = 2, M = Zn 1, Co 2 or Cd 3; n = 1, M = NH4(1+) 4) from HPO(O-i-Pr)2, sulfur and ZnO, CoCO3, CdCO3 or NH3 has been achieved.The reaction of 1 with cis- and (M = Pt or Pd) gave <(PMe2Ph)2Pt2ZnCl2> 5 and <(PMe2Ph)M3ZnCl> (M = Pd 6 or Pt 7) respectively.The crystal structures of 3, 6 and 7 have been determined.The cadmium complex 3 exists as Cd23 units linked by additional monothiophosphate ligands into polymeric chains.Complexes 6 and 7 are isomorphous and contain tetrahedral zinc centres linked to square-planar platinum atoms with polymer formation deing inhibited by the presence of PMe2Ph ligands.

Full text of DOI:10.1039/DT9950002369

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:dichlorobis(pyridine-N)zinc(II)

Cas No:17863-43-3

R&D Labs maybe for 17863-43-3

Qingdao XinYongAn Chemicals Co., Ltd

Contact:+86-532-81107967

Address:Chengyang dual-port industrial park by the sea，Qingdao
Nanjing Chemical Material Corp.(NCMC)

website:http://www.njchemm.com

Contact:0086-25-83172879

Address:B12 Technology and Innovation Building, Nanjing Tech University, No.5 New Model Road
ChangZhou Mascotchem. Co.,Ltd.

website:http://www.mascotchem.com

Contact:86-519-85010339

Address:B-802,XingBei Building,391#,Tongjiang Middle Road New District,Changzhou,JS,China
Hefei TNJ chemical industry co.,ltd

website:https://www.tnjchem.com

Contact:+86-551-65418695

Address:B911 Xincheng Business Center, Qianshan Road, Hefei Anhui China
Beijing eternalchem Co,. Ltd

Contact:+86-10-59484199

Address:No.58-A1026 Liangguan Street

Relevant to this article

Reactions of a N-acyliminium ion pool with benzylsilanes. Implication of a radical/cation/radical cation chain mechanism involving oxidative C-Si bond cleavage

Doi:10.1021/ja068589a
(2007)
(+)-1-(3S,4R)-<3-(4-Phenylbenzyl)-4-hydroxychroman-7-yl>cyclopentane Carboxylic Acid, a Highly Potent, Selective Leukotriene B₄ Antagonist with Oral Activity in the Murine Collagen-Induced Arthritis Model

Doi:10.1021/jm00046a001
(1994)
Uebergangsmetall-Carben-Komplexe CXXXXI. Untersuchungen zum Reaktionsverhalten der Carben-Komplexe cis-(CO)4(SnPh3)Re (R = ⁱPr, ^chex) gegenueber Lewis-Saeuren

Doi:10.1016/S0022-328X(00)99046-6
(1987)
Practical enantiospecific synthesis of RPR 111905: A novel Non-peptide substance P antagonist

Doi:10.1016/S0040-4039(96)02017-5
(1996)
The exploratory far-UV photochemistry of 1-methyl-1-silabicyclo[2.2.1]hept-2-ene and 2-trimethylsilylbicyclo[2.2.1]hept-2-ene

Doi:10.1016/0022-328X(95)06087-D
(1996)
Reactions of 4-dialkylamino-5-methoxy-1,2-benzoquinones in acidic media: Selective C-alkylation or N-dealkylation

Doi:10.1016/0040-4020(96)00430-9
(1996)

Article Doi