
Chemistry Letters p. 487 - 488 (1996)
Update date:2022-08-03
Topics:
Matsukura, Hiroko
Morimoto, Masamichi
Nakata, Tadashi
The 6, 6, 7-membered tricyclic ether ring system (ABC-ring) of hemibrevetoxin B was stereoselectively synthesized. The crucial steps in the present synthesis involve the ring expansion of tetrahydropyran to oxepane, 6-endo cyclization of epoxy alcohol, an
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(1996)