Chemical Communications p. 1377 - 1378 (1996)
Update date:2022-08-05
Topics:
Ueyama, Norikazu
Yamada, Yusuke
Takeda, Jiro
Okamura, Taka-Aki
Mori, Wasuke
Nakamura, Akira
Novel copper(II) dimer complexes, [Cu2{OCOC6H3Me-2-(NHCOBut)-6} 4(MeOH)(H2O)]and [CU2{OCOC6H3(NHCOBut) 2-2,6}4(MeCN)2], containing bulky, intramolecularly NH...O hydrogen-bonded carboxylate ligands, are synthesized; the former shows a distorted Cu-O-C-O-Cu structure with a magnetic exchange (-2J = 302 cm-1) between the two CuII ions while the latter has a twisted Cu-O-C-O-Cu structure with a relatively large exchange (-2J = 460 cm-1) through the NH...O hydrogen bonds.
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Doi:10.1007/BF01532299
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(1996)
