The Photolysis of Octaisopropylcyclotetrasilane; Evidence for the Formation of Hexaisopropylcyclotrisilane and Tetraisopropyldisilene

DOI: 10.1039/c39840000066

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 66 - 67 (1984)

Update date:2022-08-02

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Authors:

Watanabe, Hamao

Kougo, Yuichi

Nagai, Yoichiro

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Article abstract of DOI:10.1039/c39840000066

Irradiation of octaisopropylcyclotetrasilane (1) in a hydrocarbon solvent successively afforded hexaisopropylcyclotrisilane i2Si>3 (2) (λ_max 320 nm) and tetraisopropyldisilene i2Si=SiPrⁱ2> (3) (λ_max 400 nm) with extrusion of di-isopropylsilanediyl (4).

Full text of DOI:10.1039/c39840000066

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