η2-Alkin-Komplexe des η5-Cyclopentadienylnickel-1-norbornyls

DOI: 10.1016/S0022-328X(96)87021-5

Source and publish data:

Journal of Organometallic Chemistry p. 69 - 73 (1996)

Update date:2022-08-04

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Authors:

Lehmkuhl, Herbert

Dimitrov, Vladimir

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Article abstract of DOI:10.1016/S0022-328X(96)87021-5

Cp₂Ni reacts at -50°C with 1-norLi (1-nor = 1-norbornyl = bicyclo[2.2.1]heptane-1-yl) in THF to give CpNi-1-norbornyl (3) which is stable up to -30°C. 3 reacts with alkynes to complexes of the type CpNi (1-nor)(η²-RCCR) (R = Me (5a),

Full text of DOI:10.1016/S0022-328X(96)87021-5

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