Bryophyte constituents; 6: Synthesis of herbertene-derived sesquiterpenes from Herberta adunca

DOI: 10.1055/s-1996-4309

Source and publish data:

Synthesis p. 863 - 870 (1996)

Update date:2022-07-30

Topics:

Authors:

Eicher, Theophil

Servet, Frank

Speicher, Andreas

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1055/s-1996-4309

Efficient total syntheses are described for the racemic sesquiterpenes herbertenolide (2), α-herbertenol (3) and β-herbertenol (4) from Herberta adunca. ent-Herbertenolide [(+)-2] was prepared from enantiopure (-)-ethyl (1R)-1-methyl-2-oxocyclopentanecarboxylate (9) obtained from ethyl 2-oxocyclopentanecarboxylate (19) via reduction with baker's yeast.

Full text of DOI:10.1055/s-1996-4309

Products guided by the article

Product name:2-(2-Methoxy-5-methyl-phenyl)-1-methyl-cyclopent-2-enecarboxylic acid ethyl ester

Cas No:180211-37-4

R&D Labs maybe for 180211-37-4

Taizhou Sunny Chemical Co.,Ltd

Contact:+86-523-86920899 +86-13951172783

Address:No.11 Xingyuang road, Gaoyong Chemical Industry Park, Gaogang Jiangsu China
zhejiang huangyan wanfeng pharm chem co.ltd

Contact:+86-576- 84160728

Address:No. 5 Dazha Road, Economic,Development Zone(JiangKou), Zhejiang, China
Ji'an Hairui Natural Plant Co. Ltd.

Contact:0796-8105528

Address:Meilin industry park, Qingyuan district Ji'an City, Jiangxi Province
Ring Specialty Chemicals Inc.

website:http://www.ringchemicals.com/

Contact:+1-416-493-6870

Address:Toronto, Canada
Shanghai PuYi Chem-Tech Co.,Ltd.

Contact:+86-21-57687505-227

Address:3 Floor, Building 11, No 201 MinYi Road, Songjiang District, Shanghai 201612, China

Relevant to this article

γ-Oxygenated-α,β-unsaturated sulfones in radical cyclizations and cascade processes

Doi:10.1016/S0040-4020(97)10368-4
(1998)
Stereoselective Construction of Vicinal Diamines. Part 2. Synthesis of Indenopyrazines

Doi:10.1039/P19930001307
(1993)
Synthesis, β-hematin inhibition studies and antimalarial evaluation of new dehydroxy isoquine derivatives against Plasmodium berghei: A promising antimalarial agent

Doi:10.1016/j.ejmech.2017.10.051
(2018)
Synthesis and moessbauer characterization of octahedral iron(II) carbonyl complexes Fel₂(CO)₃L and Fel₂(CO) ₂L₂: Developing models of the [Fe]-H₂ase active site

Doi:10.1021/ic9017882
(2009)
Handedness inversion of chiral amphiphilic molecular assemblies evidenced by supramolecular chiral imprinting in mesoporous silica assemblies

Doi:10.1002/chem.201102146
(2012)
An antibody-recruiting small molecule that targets HIV gp120

Doi:10.1021/ja9057647
(2009)

Article Doi