Chemical Communications p. 1475 - 1476 (1996)
Update date:2022-07-29
Topics:
Jaquinod, Laurent
Gros, Claude
Olmstead, Marilyn M.
Antolovich, Michael
Smith, Kevin M.
(2-Nitro-5,10,15,20-tetraphenylporphyrinato)nickel(II) reacts with α-isocyanoacetic esters in the presence of DBU to give the first β-fused pyrroloporphyrins, the pyrrole ring in the fused system being shown to undergo typical pyrrole-type chemistry; the corresponding zinc(II) complex affords a novel cyclopropanochlorin (characterized by X-ray crystallography), when treated with an α-isocyanoacetic ester.
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