Palladium-catalyzed cross-coupling reactions of arylmetal compounds with β-substituted α-iodoenones and a cyclohexyl triflate

DOI: 10.1016/0040-4020(96)00489-9

Source and publish data:

Tetrahedron p. 9485 - 9498 (1996)

Update date:2022-07-30

Topics:

Authors:

Bosse, Folkert

Tunoori, Ashok Rao

Niestroj, Andre J.

Gronwald, Oliver

Maier, Martin E.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4020(96)00489-9

Electron-rich arylstannanes were found to couple with α-iodoenones in the presence of Pd₂(dba)₃ CHCl₃, a weak-coordinating ligand [AsPh₃ or Pd(o-tol)₃] and Cul (0.75-1.0 equiv) to give sterically hindered α- arylcyclohexenones 15-20. In addition, compounds 19, 22 and 23 were prepared by Suzuki coupling reactions of the cyclohexyl derivatives 7c,f and 11, respectively, with the arylboronic acid 21.

Full text of DOI:10.1016/0040-4020(96)00489-9

Products guided by the article

Product name:3-(methoxymethoxy-methyl)cyclohex-2-enone

Cas No:181041-35-0

R&D Labs maybe for 181041-35-0

AstaTech ( Chengdu) BioPharmaceutical Corp.

website:http://www.astabiochem.cn/

Contact:+86-15198215156-15198215156

Address:SICHUAN CHENGDU
Guangxi Bonger Pharmaceutical Co., Ltd

website:http://napo.lookchem.com/

Contact:+86-18817331185

Address:Donghai Industrial Zone, Tiandong Country,Guangxi,China
Wuxi Olite Chemical Co., Ltd.

Contact:86-510-82853889

Address:Rm.3732, No.18-2,Yonghe Rd.,Wuxi,Jiangsu,214023,China
Shaanxi Lighte Optoelectronics Material Co., Ltd.

Contact:+86-29-88320728-622/619/620

Address:No.55 INDUSTRY ROAD 2,XI'AN NATIONAL CIVIL AEROSPACE INDUSTRIAL PARK.XI'AN China 710065.
Chongqing maohuan Chemicals Co., Ltd

website:http://www.bschem.com

Contact:+86 13996103726

Address:Chongqing Nan'an District Tu Town

Relevant to this article

Studies on anti-MRSA parenteral cephalosporins. III. Synthesis and antibacterial activity of 7β-[2-(5-amino-1,2,4-thiadiazol-3-yl)-2(Z)- alkoxyimininoacetamido]-3-[(E)-2-(1-alkylimidazol{1,2-b]pyridazinium-6-y) thiovinyl]-3-cephem-4-carboxylates and relat

Doi:10.7164/antibiotics.54.257
(2001)
Efficient total synthesis of (-)-ilimaquinone

Doi:10.1021/jo9805192
(1998)
Novel functionalised Troger's bases: Synthesis of a new class of Troger's base analogues containing dicarboxyl functionality

Doi:10.1016/0040-4039(96)01227-0
(1996)
Synthesis and preliminary evaluation of curcumin analogues as cytotoxic agents

Doi:10.1016/j.bmcl.2010.12.020
(2011)
Convenient synthesis of hetero decalins

Doi:10.1080/00397919608003761
(1996)
α-Zinc O-vinyl carbamates as anionic Friedel-Crafts equivalents. Cross coupling reactions with aryl and heteroaryl halides and triflates

Doi:10.1016/0040-4039(96)01314-7
(1996)

Article Doi