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An abnormal Barton-Zard reaction leading to the pyrrolo[2,3-b]indole ring system

DOI: 10.1039/CC9960001909

Source and publish data:

Chemical Communications p. 1909 - 1910 (1996)

Update date:2022-08-04

Topics:

Authors:

Pelkey, Erin T.Pelkey, Erin T.

Chang, LouisChang, Louis

Gribble, Gordon W.Gribble, Gordon W.

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Article abstract of DOI:10.1039/CC9960001909

The reaction of 3-nitro-N-(phenylsulfonyl)indole 1 with ethyl isocyanoacetate 2 under the Barton-Zard pyrrole synthesis conditions gives ethyl 8-(phenylsulfonyl)-1,8-dihydropyrrolo[2,3-b]indole-2-carboxylate 3 rather than the anticipated ethyl 4-(phenylsu

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Products guided by the article

Product name:(1-Benzenesulfonyl-3-methyl-1H-indol-2-yl)-oxo-acetic acid ethyl ester

Cas No:182258-22-6

182258-22-6

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