Tetrahedron Letters p. 5853 - 5856 (1996)
Update date:2022-09-26
Topics:
Schultz, Arthur G.
Taveras, Arthur G.
Photolysis of the spiro[2.5]octa-1,4-dien-3-one 9a results in photoisomerization via the nitrile-stabilized biradical 10. Photolysis of dienone 9b in the presence of tetramethylethylene gave spiro[4.5]deca-1,4-dien-3-one 12 by cycloaddition of the intermediate biradical 11 to tetramethylethylene.
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(1996)
