Chemical Communications p. 2037 - 2038 (1996)
Update date:2022-08-05
Topics: Selective Covalently linked
Battioni
Cardin
Louloudi
Schoellhorn
Spyroulias
Mansuy
Traylor
New hybrid organic-inorganic materials are prepared by hydrolysis and polycondensation, or cocondensation with tetraethoxysilane, of iron porphyrins bearing a trifluorosilyl function; despite their insolubility, these 'metalloporphyrinosilicas' are efficient catalysts for alkene epoxidation by PhIO or ButOOH and alkane hydroxylation by PhIO, the iron porphyrinosilicas with low specific surface areas (≈ 60 m2 g-1) catalysing a shape-selective hydroxylation of alkane mixtures.
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Doi:10.1139/v96-191
(1996)Doi:10.1055/s-0037-1611662
(2019)Doi:10.1055/s-1996-4358
(1996)Doi:10.1016/j.bmcl.2006.04.045
(2006)Doi:10.1055/s-1983-30603
(1983)Doi:10.1007/BF00817265
(1996)
