Tetrahedron Letters p. 7075 - 7078 (1996)
Update date:2022-08-03
Topics:
Kuramochi, Takahiro
Asaoka, Morio
Ohkubo, Taketoshi
Takei, Hisashi
Enantioselective synthesis of the unnatural antipode of cordiaquinone B possessing a 3-substituted 2,3,4-trimethylcyclohexanone framework was accomplished starting with (4S, 5S)-4-methyl-5-trimethylsilyl-2-cyclohexen-1-one. By this synthesis, the absolute structure of (+)-cordiaquinone B has been established.
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