Tetrahedron p. 13455 - 13466 (1996)
Update date:2022-08-03
Topics:
Dondas, H. Ali
Grigg, Ronald
Thornton-Pett, Mark
Imines of 1-methyl-3-amino-1,3-dihydro-5-phenyl-(2H)-1,4-benzodiazepine-2-one undergo thermal (toluene, 110°C) or LiBr-DBU catalysed (MeCN, room temperature) regio- and stereo-specific cycloaddition to a range of achiral and chiral dipolarophiles giving racemic and homochiral spiro (pyrrolidinyl-2,3'-benzodiazepine) cycloadducts respectively in excellent yield. The reactions proceed via intermediate NH azomethine ylides and litho azomethine ylides respectively.
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Doi:10.1021/ja962117m
(1996)Doi:10.1039/jr9340001175
(1934)Doi:10.1016/S0040-4039(97)10476-2
(1998)Doi:10.1016/S0040-4039(00)60507-5
(1993)Doi:10.7164/antibiotics.49.1031
(1996)Doi:10.1002/anie.201510003
(2016)
