Sulfoxide-controlled S(N)2' displacements between cyanocuprates and epoxy vinyl sulfoxides

DOI: 10.1016/0040-4039(96)01817-5

Source and publish data:

Tetrahedron Letters p. 8031 - 8034 (1996)

Update date:2022-08-03

Topics:

Authors:

Marino, Joseph P.

Anna, Laura J.

Fernandez De La Pradilla, Roberto

Martinez, Maria Victoria

Montero, Carlos

Viso, Alma

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(96)01817-5

Readily available enantiomerically pure epoxy vinyl sulfoxides, 10-13 and 15 undergo highly regio- and stereoselective S(N)2' displacements with alkyl cyanocuprates. The sulfinyl auxiliary controls the anti-syn stereochemistry of the process.

Full text of DOI:10.1016/0040-4039(96)01817-5

Products guided by the article

Product name:4-Hepten-3-ol, 2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-6-methyl-4-[(S)-(4-methylphenyl) sulfinyl]-, (2S,3R,4E)-

Cas No:184850-68-8

R&D Labs maybe for 184850-68-8

Wuhan Chemwish Technology Co., Ltd

website:http://www.chemwish.com/

Contact:+86-27-67849912

Address:Room 1311, Unit 2, Block1, Innovation Road East Lake High-tech Development Zone Wuhan, Hubei，P.R. China
Ji'nan Orgachem Pharmaceutical Co.,Ltd

Contact:+86-531-82687810

Address:Jinan
ClickChem Technology Co., Limited

Contact:+86-0310-6519966/0531-52893837

Address:No.750 Shunhua Road, High-Tech Zone, Jinan city, Shandong China
Zhejiang Chemline International Co., Ltd.

Contact:+86-571-88062298

Address:Hengdian Industry Area, Dongyang, Zhejiang, China
QINGDAO HONG JIN CHEMICAL CO.,LTD.

website:http://www.hongjinchem.com

Contact:+86-532-83657313

Address:2ND Building, 8 Shangqing Road, Qingdao, Shandong Province, China.

Relevant to this article

Hypervalent Iodine Oxidations: Structure and Kinetics of the Reactive Intermediates in the Oxidation of Alcohols and 1,2-diols by o-Iodoxybenzoic Acid (IBX) and Dess-Martin Periodinane. A Comparative 1H-NMR Study

Doi:10.1021/jo961044m
(1996)
2-Aminoalcohol immunosuppressants: Structure-activity relationships

Doi:10.1016/S0960-894X(96)00487-8
(1996)
Unusual ligand-induced reductive elimination in Cp*W(NO)(H)[η²-PPh₂C₆H₄]: A route to the extremely strong π-donor fragment Cp*W(NO)(PPh₃)

Doi:10.1021/ja9635037
(1997)
Species-specific glucosylation of DIMBOA in larvae of the rice armyworm

Doi:10.1271/bbb.80903
(2009)
Doi:10.1021/ja01861a019
(1940)
Total synthesis and revision of stereochemistry of cyclodidemnamide, a novel cyclopeptide from the marine ascidian Didemnum molle

Doi:10.1016/S0040-4039(98)00365-7
(1998)

Article Doi