Sulfoxide-controlled S(N)2' displacements between cyanocuprates and epoxy vinyl sulfoxides

DOI: 10.1016/0040-4039(96)01817-5

Source and publish data:

Tetrahedron Letters p. 8031 - 8034 (1996)

Update date:2022-08-03

Topics:

Authors:

Marino, Joseph P.

Anna, Laura J.

Fernandez De La Pradilla, Roberto

Martinez, Maria Victoria

Montero, Carlos

Viso, Alma

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Article abstract of DOI:10.1016/0040-4039(96)01817-5

Readily available enantiomerically pure epoxy vinyl sulfoxides, 10-13 and 15 undergo highly regio- and stereoselective S(N)2' displacements with alkyl cyanocuprates. The sulfinyl auxiliary controls the anti-syn stereochemistry of the process.

Full text of DOI:10.1016/0040-4039(96)01817-5

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