Synthesis and reactivity of a 3-vinylidenepiperidine as a model study of α-allenic amines

DOI: 10.3987/com-96-7563

Source and publish data:

Heterocycles p. 2415 - 2424 (1996)

Update date:2022-09-26

Topics:

Authors:

Solé, Daniel

García-Rubio, Silvina

Bosch, Joan

Bonjoch, Josep

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Article abstract of DOI:10.3987/com-96-7563

4-Acetonyl-1-benzyl-3-vinylidenepiperidine (8), prepared by cyclization of propargylic silane (7), was used as a model to study the usefulness of the allene moiety as a precursor of the two-carbon chain present in the piperidine ring of Strychnos alkaloids.

Full text of DOI:10.3987/com-96-7563

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