Chemistry of vinylidene complexes XII 1. Transmetalation of the μ-vinylidene ligand in the reaction of Cp(CO)2MnPt(μ-C=CHPh)(dppp) with Fe2(CO)9. Formation of new PtFe, PtFe2 and PtFe3 complexes

DOI: 10.1016/S0022-328X(96)06432-7

Source and publish data:

Journal of Organometallic Chemistry p. 81 - 85 (1996)

Update date:2022-08-02

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Authors:

Antonova, Alla B.

Johansson, Alfred A.

Deykhina, Nina A.

Korniyets, Evgeny D.

Pavlenko, Nina I.

Burmakina, Galina V.

Rubaylo, Anatoly I.

Ginzburg, Allan G.

Petrovskii, Pavel V.

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Article abstract of DOI:10.1016/S0022-328X(96)06432-7

The reaction between [Fe₂(CO)₉] and [Cp(CO)₂MnPt(μ-C=CHPh)(dppp)] (1), where dppp is Ph₂P(CH₂)₃PPh₂) proceeds stepwise, initially through transmetalation of the bridging vinylide

Full text of DOI:10.1016/S0022-328X(96)06432-7

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Product name:(Fe(CO)4)2Pt((C₆H₅)2P(CH₂)3P(C₆H₅)2)

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