Reactivity of benzylic acylammonium chlorides. A novel method for the synthesis of N-phenacylamides

Article abstract of DOI:10.1080/00397919708004799

Tertiary amines 1 reacted with acid chlorides 2 to give corresponding benzyl chlorides and N-phenacylamides 4. Counterion in species 3 attacked preferentially the benzylic methylene. Effect of substituents in the benzyl group on the reactivity of acylammo

Full text of DOI:10.1080/00397919708004799

This article was downloaded by: [University of Arizona]
On: 22 January 2013, At: 02:43
Publisher: Taylor & Francis
Informa Ltd Registered in England and Wales Registered Number:
1072954 Registered office: Mortimer House, 37-41 Mortimer Street,
London W1T 3JH, UK
Synthetic Communications:
An International Journal
for Rapid Communication of
Synthetic Organic Chemistry
Publication details, including instructions for
authors and subscription information:
http://www.tandfonline.com/loi/lsyc20
Reactivity of Benzylic
Acylammonium Chlorides.
A Novel Method for
the Synthesis of N-
Phenacylamides
Necdet Coşkun a & Fatma Tirli a
a Department of Organic Chemistry, Uludag
University, Bursa, 16059, TURKEY
Version of record first published: 19 Aug 2006.
To cite this article: Necdet Coşkun & Fatma Tirli (1997): Reactivity of Benzylic
Acylammonium Chlorides. A Novel Method for the Synthesis of N-Phenacylamides,
Synthetic Communications: An International Journal for Rapid Communication of
Synthetic Organic Chemistry, 27:1, 1-9
To link to this article: http://dx.doi.org/10.1080/00397919708004799
PLEASE SCROLL DOWN FOR ARTICLE
Full terms and conditions of use: http://www.tandfonline.com/page/
terms-and-conditions
This article may be used for research, teaching, and private study
purposes. Any substantial or systematic reproduction, redistribution,
reselling, loan, sub-licensing, systematic supply, or distribution in any
form to anyone is expressly forbidden.

The publisher does not give any warranty express or implied or make
any representation that the contents will be complete or accurate or
up to date. The accuracy of any instructions, formulae, and drug doses
should be independently verified with primary sources. The publisher
shall not be liable for any loss, actions, claims, proceedings, demand, or
costs or damages whatsoever or howsoever caused arising directly or
indirectly in connection with or arising out of the use of this material.