Synthesis of a novel diazo functionalised oxime ligand and its Cu(II) and Fe(III) complexes

Article abstract of DOI:10.1080/00945719708000153

N-Phenyl-3-oxo-butanamide, (1), which is used in dyes and pigment synthesis, on reaction with hydroxylamine gives N-phenyl-3-hydroxyimino-butanamide (2). This compound reacts with diazonium salts to give diazo products which coordinate to copper(II) and iron(III). The intermediate obtained from the preparation of the ligand, the ligand itself and the metal complexes were characterised by magnetic susceptibility, spectroscopic techniques such as IR, ¹H NMR, UV-Vis. and microanalytical data.

Full text of DOI:10.1080/00945719708000153

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Synthesis and Reactivity in
Inorganic and Metal-Organic
Chemistry
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Synthesis of a Novel Diazo
Functionalised Oxime Ligand
and Its Cu(II) and Fe(III)
Complexes
Bilgehan Güzel a , Osman Serindag a & Selahattin
Serin a
a Çukurova Üniversitesi, Fen Edebiyat Fakultesi
Kimya Bölümü , 01330, Adana, Turkey
Published online: 22 Aug 2006.
To cite this article: Bilgehan Güzel , Osman Serindag & Selahattin Serin (1997)
Synthesis of a Novel Diazo Functionalised Oxime Ligand and Its Cu(II) and Fe(III)
Complexes, Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 27:2,
301-309, DOI: 10.1080/00945719708000153
To link to this article: http://dx.doi.org/10.1080/00945719708000153
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