A novel MNOP3 metallacycle. Crystal and molecular structure of cis-[PtCl2{Ph2POP(Ph)2NPPh 2-P,P′}]

DOI: 10.1016/S0277-5387(96)00458-5

Source and publish data:

Polyhedron p. 1563 - 1566 (1997)

Update date:2022-08-04

Topics:

Authors:

Slawin, Alexandra M. Z.

Smith, Martin B.

Woollins, J. Derek

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Article abstract of DOI:10.1016/S0277-5387(96)00458-5

Thermolysis of cis-[PtCl₂{Ph₂PNHP(O)Ph₂-P}₂] (1) in refluxing xylene gives cis-[PtCl₂{Ph₂POP (Ph)₂NPPh₂-P,P′}] (2) containing the first example of an MNOP₃ metallacycle. Compound 2 has been characterized by multinuclear NMR spectroscopy (¹H, ³¹P-{¹H} and ¹⁹⁵Pt-{¹H}), IR spectroscopy and X-ray crystallography. The related palladium(II) complex cis-[PdCl₂{Ph₂POP(Ph)₂NPPh ₂-P,P′}] (3) was similarly prepared.

Full text of DOI:10.1016/S0277-5387(96)00458-5

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