A stereoselective total synthesis of (-)-rishitin

DOI: 10.1016/S0040-4039(97)00228-1

Source and publish data:

Tetrahedron Letters p. 1889 - 1892 (1997)

Update date:2022-08-03

Topics:

Authors:

Chen, Jiong

Marx, John N.

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Article abstract of DOI:10.1016/S0040-4039(97)00228-1

A new synthesis of (-)-rishitin (1) is reported, starting with chiral pool molecules. The crucial step is a stereoselective vinyl radical cyclization, which gives a 10:1 ratio of 21 to 22.

Full text of DOI:10.1016/S0040-4039(97)00228-1

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