Tetrahedron Letters p. 1889 - 1892 (1997)
Update date:2022-08-03
Topics:
Chen, Jiong
Marx, John N.
A new synthesis of (-)-rishitin (1) is reported, starting with chiral pool molecules. The crucial step is a stereoselective vinyl radical cyclization, which gives a 10:1 ratio of 21 to 22.
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Doi:10.1211/0022357011778043
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