Tetrahedron Letters p. 2787 - 2790 (1997)
Update date:2022-08-05
Topics:
Farmer, Jay J.
Attygalle, Athula B.
Smedley, Scott R.
Eisner, Thomas
Meinwald, Jerrold
Samples of (X) and (S)-epilachnene [(5Z)-11-propyl-12-azacyclotetradec-5-en olide] were synthesized from (R) and (S)-norvaline. The diastereomeric α-methoxy-α-trifluoromethylphenylacetyl amides of these synthetic samples, prepared using (S) α-methoxy-α-trifluoromethylphenylacetyl chloride, were well resolved by gas chromatography. Analogous derivatization and gas chromatographic analysis of a sample of epilachnene from the pupal secretion of the coccinellid beetle, Epilachna varivestis, established that the natural product is (S)-epilachnene.
View MoreSynochem Ingredients Corp., Ltd.
Contact:+86-512-5636 2180
Address:Zhangjiagang Free Trade Zone
Contact:86-607-68073220
Address:1 ave na road jiahua st
Contact:+86-371-86058576
Address:NO.32, Jingsan Road, Zhengzhou, China
SHANXI JINJIN CHEMICAL INDUSTRIAL CO.,LTD
website:http://www.jinjingroup.com
Contact:86-574-13989382828
Address:Economic And Technological Development Zone,Hejin?City,Shanxi Province?,China
Contact:86-513-84128750/13773795976
Address:No.48.Youyi West Road ,Rudong Development Zone,Jiangsu Province,China
Doi:10.1016/j.jfluchem.2010.02.003
(2010)Doi:10.1016/S0040-4020(99)00881-9
(1999)Doi:10.1016/j.tet.2009.01.029
(2009)Doi:10.1021/om100154w
(2010)Doi:10.1021/om971109r
(1998)Doi:10.1016/S0008-6215(97)00011-6
(1997)
