STEREOSPECIFIC SYNTHESIS OF CARBOCYCLIC NUCLEOSIDES FROM 2-AZABICYCLO-HEPTAN-3-ONES VIA SODIUM BOROHYDRIDE MEDIATED CARBON-NITROGEN BOND CLEAVAGE

DOI: 10.1016/S0040-4039(00)99542-X

Source and publish data:

Tetrahedron Letters p. 1645 - 1648 (1989)

Update date:2022-07-30

Topics:

Authors:

Katagiri, Nobuya

Muto, Makoto

Kaneko, Chikara

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Article abstract of DOI:10.1016/S0040-4039(00)99542-X

New synthons for carbocyclic nucleosides have been synthesized from 2-azabicyclo<2.2.1>hept-5-en-3-one readily available from cyclopentadiene, through introduction of an electron-withdrawing substituent at the 2-position followed by reduction with sodium

Full text of DOI:10.1016/S0040-4039(00)99542-X

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Product name:2-(toluene-4-sulfonyl)-2-aza-bicyclo[2.2.1]heptan-3-one

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