Remote asymmetric induction in reactions of 5-alkoxyalk-2-enylsilanes and aldehydes promoted by tin(IV) chloride

DOI: 10.1016/S0040-4039(97)00358-4

Source and publish data:

Tetrahedron Letters p. 2387 - 2390 (1997)

Update date:2022-08-03

Topics:

Authors:

Brain, Christopher T.

Thomas, Eric J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(97)00358-4

Following observations on remote asymmetric induction using allylstannanes, 5-benzyloxy-4-methylpent-2-enylsilanes are also found to react with aldehydes with modest levels of 1,5-induction after treatment with tin(IV) chloride. Transmetallation to give intermediate allyltin trihalides may be involved.

Full text of DOI:10.1016/S0040-4039(97)00358-4

Products guided by the article

Product name:Methanesulfonic acid 2-benzenesulfonyl-1-((S)-2-benzyloxy-1-methyl-ethyl)-3-trimethylsilanyl-propyl ester

Cas No:190134-25-9

R&D Labs maybe for 190134-25-9

ZhangJiaGang YaRui Chemical Co.,Ltd.

Contact:0512-58360968

Address:China JiangSu Province Zhang Jia Gang City YangShe Oriental Plaza Building 10 B307
Haitong Chemical Industrial Co.,Ltd.

website:https://www.haitonglongwin.com/

Contact:+86-022-66221018

Address:18-701, No.99, The 4th Street, TEDA,
ABA Chemicals (Shanghai) Limited

Contact:021- 5115 9199-232

Address:Suite 18D, #201 Ningxia Road,
Beijing Tianjia Chemical Science & Technology Co.,Ltd

Contact:86-0550-2392698

Address:No.388, Shiliang Road (East),
Tianjin Dongchang Fine Chemical Industry Co., Ltd.

Contact:+86-22-29894595

Address:Economic Developing Zone, Ji County, Tianjin, China

Relevant to this article

Synthesis of a novel fused tricyclic quinolone system via oxidation of 1,2,3,4-tetrahydro-β-carbolines

Doi:10.1016/S0040-4039(97)00542-X
(1997)
Synthetic studies on maduropeptin chromophore 2. Synthesis of the madurosamine aryl amide and the C1'-C9' fragments

Doi:10.1016/S0040-4039(97)00724-7
(1997)
Thermal (iodide) and photoinduced electron-transfer catalysis in biaryl synthesis via aromatic arylations with diazonium salts

Doi:10.1021/ja970599b
(1997)
Structure-activity relationships study at the 3'-N position of paclitaxel-part 1: Synthesis and biological evaluation of the 3'-(t)-butylaminocarbonyloxy bearing paclitaxel analogs

Doi:10.1016/S0960-894X(97)10142-1
(1997)
P-H bond activation of primary phosphine-boranes: Access to α-hydroxy and α,α′-dihydroxyphosphine-borane adducts by uncatalyzed hydrophosphination of carbonyl derivatives

Doi:10.1016/S0022-328X(96)06640-5
(1997)
Pesticides labelled with ¹⁴C.: IV. Synthesis of Diuron and Linuron in various positions

Doi:10.1002/(SICI)1099-1344(199607)38:7<661::AID-JLCR876>3.0.CO;2-B
(1996)

Article Doi