Remote asymmetric induction in reactions of 5-alkoxyalk-2-enylsilanes and aldehydes promoted by tin(IV) chloride

DOI: 10.1016/S0040-4039(97)00358-4

Source and publish data:

Tetrahedron Letters p. 2387 - 2390 (1997)

Update date:2022-08-03

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Authors:

Brain, Christopher T.

Thomas, Eric J.

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Article abstract of DOI:10.1016/S0040-4039(97)00358-4

Following observations on remote asymmetric induction using allylstannanes, 5-benzyloxy-4-methylpent-2-enylsilanes are also found to react with aldehydes with modest levels of 1,5-induction after treatment with tin(IV) chloride. Transmetallation to give intermediate allyltin trihalides may be involved.

Full text of DOI:10.1016/S0040-4039(97)00358-4

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