Remote asymmetric induction in reactions of 5-alkoxyalk-2-enylsilanes and aldehydes promoted by tin(IV) chloride

DOI: 10.1016/S0040-4039(97)00358-4

Source and publish data:

Tetrahedron Letters p. 2387 - 2390 (1997)

Update date:2022-08-03

Topics:

Authors:

Brain, Christopher T.

Thomas, Eric J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(97)00358-4

Following observations on remote asymmetric induction using allylstannanes, 5-benzyloxy-4-methylpent-2-enylsilanes are also found to react with aldehydes with modest levels of 1,5-induction after treatment with tin(IV) chloride. Transmetallation to give intermediate allyltin trihalides may be involved.

Full text of DOI:10.1016/S0040-4039(97)00358-4

Products guided by the article

Product name:Methanesulfonic acid 2-benzenesulfonyl-1-((S)-2-benzyloxy-1-methyl-ethyl)-3-trimethylsilanyl-propyl ester

Cas No:190134-25-9

R&D Labs maybe for 190134-25-9

Richest Group Ltd.

Contact:+86 21 5017 5386

Address:No 999,Jiangyue Rd, Minhang Dist ,201114,Shanghai ,China
Shanghai Coupling Pharmaceutical R&D Co., Ltd.(expird)

Contact:+86 021 50106671

Address:403 Room No.4 Buiding, No. 526 Ruiqing Road, Shanghai Zhangjiang Hi-Tech Park
LIAOYANG TENGYUAN FOOD ADDITIVE FACTORY

Contact:+86-419-5807666

Address:Haodianzi village,Hanling Town,Liaoyang county
Tianjin Chemsyntech Chemical Co., Ltd

Contact:+86-22-60872258

Address:Haitai green industry base in Tianjin, K1,5-601
Jinan Boss Chemical Industry Co., Ltd.【revoke the business license】

website:http://www.chemboss.com.cn

Contact:+86-531-58591595

Address:No2.Hualong Road, Jinan, China

Relevant to this article

Synthesis of a novel fused tricyclic quinolone system via oxidation of 1,2,3,4-tetrahydro-β-carbolines

Doi:10.1016/S0040-4039(97)00542-X
(1997)
Synthetic studies on maduropeptin chromophore 2. Synthesis of the madurosamine aryl amide and the C1'-C9' fragments

Doi:10.1016/S0040-4039(97)00724-7
(1997)
Thermal (iodide) and photoinduced electron-transfer catalysis in biaryl synthesis via aromatic arylations with diazonium salts

Doi:10.1021/ja970599b
(1997)
Structure-activity relationships study at the 3'-N position of paclitaxel-part 1: Synthesis and biological evaluation of the 3'-(t)-butylaminocarbonyloxy bearing paclitaxel analogs

Doi:10.1016/S0960-894X(97)10142-1
(1997)
P-H bond activation of primary phosphine-boranes: Access to α-hydroxy and α,α′-dihydroxyphosphine-borane adducts by uncatalyzed hydrophosphination of carbonyl derivatives

Doi:10.1016/S0022-328X(96)06640-5
(1997)
Pesticides labelled with ¹⁴C.: IV. Synthesis of Diuron and Linuron in various positions

Doi:10.1002/(SICI)1099-1344(199607)38:7<661::AID-JLCR876>3.0.CO;2-B
(1996)

Article Doi