Journal of Organometallic Chemistry p. 127 - 133 (1997)
Update date:2022-09-26
Topics:
Pietschnig, Rudolf
Niecke, Edgar
Nieger
Airola, Karri
P-Ferrocenyl-substituted alkylidenephosphanes have been prepared and characterized spectroscopically. Their ready conversion to the corresponding acylphosphanes and 1,2-diacyldiphosphanes, as well as a new type of phosphirene synthesis are presented. The X-ray structure of the tetraferrocenyl-substituted diacyldiphosphane has been investigated. Furthermore, P-ferrocenyl iminophosphanes and their complexation behaviour are described. Diferrocenyldiphosphene, which is known to be unstable, has been stabilized by complexation; this has been confirmed by NMR-spectroscopy and X-ray structure analysis.
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Doi:10.1039/a607545b
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(1997)
