Metal-carbon multiple bonds: Synthesis, structure, and electrochemistry of chromium aminocarbyne and phenylcarbyne complexes bearing phosphine or alkyl isonitrile ligands

DOI: 10.1016/S0022-328X(96)06749-6

Source and publish data:

Journal of Organometallic Chemistry p. 207 - 218 (1997)

Update date:2022-09-26

Topics:

Authors:

Filippou, Alexander C.

Woessner, Dirk

Kociok-Koehn, Gabriele

Hinz, Isolde

Gruber, Lutz

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Article abstract of DOI:10.1016/S0022-328X(96)06749-6

The synthesis, structure and cyclic voltammetry studies of neutral and cationic chromium carbyne complexes bearing phosphine or alkyl isonitrile ligands are reported. Treatment of cis-X(CO)₂(pic)₂Cr≡CNⁱPr₂ (pic:

Full text of DOI:10.1016/S0022-328X(96)06749-6

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Product name:[fac-(CO)2(PMe₂Ph)3Cr_.tplbond.CN(i-Pr)2]PF₆

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