Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 2410 - 2415 (1989)
Update date:2022-07-29
Topics:
Kasatkin, A. N.
Romanova, T. Yu.
Tsypyshev, O. Yu.
Tolstikov, G. A.
Lomakina, S. I.
Aryl organomanganese compounds ArMnX and Ph3MnLi (Ar = Ph, p-MeC6H4, p-MeOC6H4, p-ClC6H4, p-BrC6H4, α-naphthyl; X = Cl, Br) react with alkenyl iodides RR1C=CR2I (R = H, Pr, Bu, i-Bu, C6H13, CH2=CHCH2, Ph; R1 = H, Pr, C5H11; R2 = H, Pr, SiMe3) in THF at 0-20 deg C to give cross-coupling products RR1C=CR2Ar in high yields.
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