A convenient preparative method for α-trifluoromethyl amines

DOI: 10.1016/S0022-1139(96)03574-9

Source and publish data:

Journal of Fluorine Chemistry p. 15 - 19 (1997)

Update date:2022-09-26

Topics:

Authors:

Watanabe, Shoji

Fujita, Tsutomu

Sakamoto, Masami

Hamano, Hiroyuki

Kitazume, Tomoya

Yamazaki, Takashi

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Article abstract of DOI:10.1016/S0022-1139(96)03574-9

α-Trifluoromethyl amines (IV) were prepared in three steps: preparation of α-trifluoromethyl ketones (I), their conversion to benzyloximes (II), and reduction of the oximes (II) with lithium aluminium hydride and sodium methoxide. For example, α-trifluoromethyltridecylamine was obtained from the reduction of trifluoromethyl dodecyl ketone benzyl oxime. Elsevier Science S.A.

Full text of DOI:10.1016/S0022-1139(96)03574-9

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Product name:2-Dodecanone, 1,1,1-trifluoro-, O-(phenylmethyl)oxime

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