Zeitschrift fur Anorganische und Allgemeine Chemie p. 1093 - 1097 (1997)
Update date:2022-08-03
Topics:
Braunschweig, Holger
Dirk, Regina
Englert, Ulli
The new α,ω-[boryl(organyl)]phosphane o-Ph2PC6H4CH2B(NMe2) 2 (10) was obtained in good yields from the reaction of ClB(NMe2)2 with o-Ph2PC6H4CH2Li(tmeda). Five derivatives of 10 were obtained by substituting the boron-bound amino groups by reactions with MeOH, BCl3, HCl, and LiAlH4, respectively, in particular, o-Ph2(HCl)PC6H4CH2BCl 2(HNMe2) (10 e) which shows a unique P-H-Cl-H-N unit. Compound 10 and its derivatives were characterized by multinuclear NMR methods, mass spectra, and elemental analyses. In addition, the structure of 10 e·1.5C6H6 was determined by single crystal X-ray diffraction.
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(1997)
