Tributyltin chloride-sodium cyanoborohydride mediated tandem radical cyclisation-reductive demethoxylation sequence

DOI: 10.1016/S0040-4020(97)00658-3

Source and publish data:

Tetrahedron p. 10479 - 10488 (1997)

Update date:2022-08-03

Topics:

Authors:

Srikrishna

Viswajanani

Yelamaggad

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(97)00658-3

Reaction of the bromoketals 3, 7a-g and 11 with tri-n-butyltin chloride and sodium cyanoborohydride in the presence of a catalytic amount of AIBN furnished the ethers 5, 8a-g and 13 via a tandem sequence comprising of a radical cyclisation reaction and tri-n-butylhalostannane and sodium cyanoborohydride mediated reductive demethoxylation of the resulting cyclic ketals.

Full text of DOI:10.1016/S0040-4020(97)00658-3

Products guided by the article

Product name:Benzene, 1-[3-(2-bromo-1-methoxy-1-methylethoxy)-1-butenyl]-4-methoxy-, (E)-

Cas No:194493-43-1

R&D Labs maybe for 194493-43-1

New Forms

Contact:+31-24-3886056

Address:Binderskampweg 29 Unit 36
Shanghai KFSL Pharmaceutical Technology Co.,Ltd.

Contact:+86-21-39971718

Address:859 jiadingchengliu shanghai
Phytomarker Ltd.(expird)

Contact:+86-22-26358246

Address:601-4-20, Fujiayuan, Tiantai Road, Hebei District, Tianjin, China
shanghai meicheng chemical co .,ltd(expird)

Contact:+86-21-50677091

Address:Room 302, Building 7, No.1000, Jinhai Road
NANCHANG QINZHI SCI&TEC.CO.,LTD(expird)

Contact:+86-13687004106

Address:Hero South Road,Hero Zone,Nanchang,Jiangxi,China

Relevant to this article

Tetrakis(trimethylsilyl) ethenylidene-1,1-bisphosphonate: A mild and convenient Michael acceptor for the synthesis of 2-aminoethylidene-1,1- bisphosphonic acids and their potassium salts

Doi:10.1055/s-0030-1260566
(2011)
Design and synthesis of monocyclic β-lactams as mechanism-based inhibitors of human cytomegalovirus protease

Doi:10.1016/S0960-894X(98)00032-8
(1998)
2'-C-Methyl analogues of selective adenosine receptor agonists: Synthesis and binding studies

Doi:10.1021/jm9707737
(1998)
Stoichiometric and catalytic conversion of alkynes to conjugated (Z,Z)-dienes and cyclopentadienes via palladacyclopentadienes and 1,3-dienylpalladium(II) halide and triorganopalladium(IV) halide compounds containing chelating nitrogen ligands

Doi:10.1021/om970977l
(1998)
Synthesis and thermal behaviour of pentamethylcyclopentadienylrhodium(III) complexes with anilines

Doi:10.1016/S0040-6031(97)00315-8
(1997)
Carbocycles via enantioselective inter- and intramolecular iridium-catalysed allylic alkylations

Doi:10.1039/b503713a
(2005)

Article Doi