Tetrahedron Letters p. 7891 - 7892 (1997)
Update date:2022-08-03
Topics:
Mori, Kenji
Matsui, Junichi
Methyl (S)-citronellate (2) was converted to (3aR,8S,8bS,2'R)-(+)- sorgolactone (1a) by employing the radical cyclization of 6 to 7 as the key- step. Three other stereoisomers (1b, 1c and 1d) of sorgolactone were also prepared. The CD spectrum of la was in accord with that reported for the natural product.
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