Russian Chemical Bulletin p. 1380 - 1382 (1999)
Update date:2022-08-04
Topics:
Vasil'eva
Lapitskaya
Pivnitsky
In contrast with androsta-1,4-diene-3α/β,17β-diol, its 3-O-methyl ether is transformed upon C(3)-deprotonation into the corresponding 3-methylene steroid with migration of the O-methyl group on the steroid skeleton (by the scheme of Wittig rearrangement) rather than eliminating the 19-methyl group.
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(2019)Doi:10.1016/S0040-4039(97)10389-6
(1997)Doi:10.1021/ic970670e
(1998)Doi:10.1021/ja01313a028
(1935)Doi:10.1021/jo971380i
(1998)Doi:10.1139/v97-158
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