Chemical and Pharmaceutical Bulletin p. 1739 - 1744 (1997)
Update date:2022-09-26
Topics:
Murakami, Yasuoki
Watanabe, Toshiko
Suzuki, Hideharu
Kotake, Nobuyo
Takahashi, Tomoko
Toyonari, Kiyono
Ohno, Masami
Takase, Kyoko
Suzuki, Takayuki
Kondo, Kazuhiro
In the Hemetsberger-Knittel reaction for indole synthesis, the intermediate ethyl 2-azido-3-hydroxy-3-aryl-propionate (4) was found to be formed in the reaction of arylaldehyde 1 with ethyl azidoacetate at a lower temperature (-30°C) as the main product,
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