Tetrahedron Letters p. 4729 - 4731 (2000)
Update date:2022-07-30
Topics:
Wittman, Mark D.
Kadow, John F.
Vyas, Dolatrai M.
The stereospecific synthesis of 6-α-hydroxy paclitaxel 10, the major human metabolite of paclitaxel, is described. The 6,7-α-diol 4, obtained from paclitaxel, is converted to the 6,7-β-cyclic sulfate followed by nitrate addition and reduction to afford the title compound. (C) 2000 Elsevier Science Ltd.
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