Tetrahedron Letters p. 389 - 392 (1998)
Update date:2022-07-30
Topics:
Nishizawa, Mugio
Imagawa, Hiroshi
Hyodo, Ikumi
Takeji, Miho
Morikuni, Eiko
Asoh, Kohsuke
Yamada, Hidetoshi
Bicyclo[9.3.1]pentadecatriene derivative 4 which corresponds to a precursor of taxol in a biomimetic entry was constructed by means of TiCl4-Zn promoted McMurry cyclization and Mitsunobu inversion. Treatment of 4 with mercuric triflate afforded an unexpected rearrangement-transannular cyclization product 5.
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(2002)Doi:10.1016/S0022-328X(97)00188-5
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(1998)
